石煤钒矿低温硫酸熟化-水浸提钒工艺

    Low Temperature Sulfuric Acid Ripening-water Leaching for Vanadium Extraction from Stone Coal Vanadium Ore

    • 摘要: 这是一篇冶金工程领域的论文。以陕西某地含钒矿物为绢云母、伊利石的石煤钒矿为研究对象,采用低温硫酸熟化-水浸工艺提钒,考查了熟化温度、熟化时间、硫酸用量、氯化钠用量,浸出温度、浸出时间及浸出液固比对钒浸出率的影响。结果表明:向石煤钒矿中加入25%的硫酸、0.8%的氯化钠,在130 ℃下熟化8 h,熟化样品在浸出温度 55 ℃、液固比 1.5∶1的条件下浸出时间2 h,钒浸出率可达89%。这说明采用低温(130 ℃)硫酸熟化-水浸工艺提取石煤型钒矿是可行的。

       

      Abstract: This is an article in the field of metallurgical engineering. The vanadium ore with vanadium containing sericite and illite in Shaanxi province was taken as the research object, low-temperature sulfuric acid ripening-water leaching process was used to extract vanadium. The effects of ripening temperature, ripening time, sulfuric acid dosage, sodium chloride dosage, leaching temperature, leaching time and liquid-solid ratio on vanadium leaching rate were investigated. The results show when 25% sulfuric acid and 0.8% sodium chloride are added to the stone coal vanadium ore, the sample is aged at 130 ℃ for 8 h, and the sample is leached at 55 ℃ for 2 h under the conditions of liquid-solid ratio of 1.5∶1, the vanadium leaching rate can reach more than 89%. This indicates that it is feasible to adopt low temperature sulfuric acid ripening and water leaching process to extract stone coal type vanadium ore.

       

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