Abstract: This is a paper in the field of metallurgical engineering. Pellets were prepared from vanadium and titanium magnetite concentrates from Liaoxi, and the preheating characteristics and roasting characteristics of the pellets were studied. Results show that the strength of preheating ball can reach 819 N when preheating for 15 min at 900℃, and the strength of the ball reached 3020 N at 1100℃ for 15 min under the optimum preheating system. The oxidation degree of the pellet is 97% at 900℃ for 15 min, and the temperature has a stronger influence on the oxidation degree than time.With the increase of oxidation temperature, with the increase of preoxidation temperature, magnetite in the pellets changes into hematite and ilmenite into ferrobrookite. With the increase of calcination temperature, the crystal in pellet grows up, the porosity decreases and the structure becomes denser.