双极膜电渗析淡化海砂同步回收资源

    Simultaneous Sea Sand Desalination and Resources Recovery Using the Bipolar Membrane Electrodialysis

    • 摘要: 【目的】为实现海砂淡化同步回收淡水、酸和碱等资源,【方法】以期利用电场作用下的水分子解离和离子过膜迁移原理,以海砂为处理对象,构建双极膜电渗析反应器,进行双极膜电渗析淡化海砂同步回收实验。【结果】在进料砂水质量比1∶1和电流密度10 mA/cm2下,海砂中氯化物的去除率达到98% ± 1%,出砂氯化物含量符合《建设用砂》(GB/T 14684-2022)标准。同时,从脱盐室回收了pH = (8.43 ± 0.30)和电导率=(2.30 ± 0.49) mS/cm的淡水,从产酸室回收了H+浓度为0.057 mol/L的酸溶液,从产碱室回收了OH-浓度为0.025 mol/L的碱溶液。【结论】双极膜电渗析是一种具有应用前景的海砂淡化同步回收资源的新方法。

       

      Abstract: Objective To achieve the simultaneous recovery of fresh water, acid and alkali resources through desalination of sea sand, Method it is expected to utilize the principle of water molecule dissociation and ion transmembrane migration at the action of an electric field, taking sea sand as the treatment object, to construct a bipolar membrane electrodialysis reactor and conduct experiments on the simultaneous recovery of desalinated sea sand through bipolar membrane electrodialysis. Result With sand-to-water ratio in quality of 1:1 and current density of 10 mA/cm2, Cl- removal efficiency in the sea sand was 98% ± 1% in the BMED, so that Cl- content in desalinated sea sand reached the standard of sand for construction (GB/T 14684-2022). Meanwhile, a stream of fresh water with pH = 8.43 ± 0.30 and conductivity as 2.30 ± 0.49 mS/cm was recovered from the desalination chamber. A stream of acid solution with H+ concentration of 0.057 mol/L was recovered from the acid production chamber. A stream of alkali solution with OH- concentration of 0.025 mol/L was recovered from the alkali production chamber. Conclusion BMED is a promising method for simultaneous sea sand desalination and resources recovery.

       

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