热活化-化学活化对水库底泥-水泥复合胶凝材料性能的影响

    Effect of Thermal Activation and Chemical Activation on Properties of Reservoir Sediment-cement Composite Cementitious Materials

    • 摘要: 【目的】水库底泥数量众多,且呈流塑状,承载能力较差,处理较困难,因此急需寻找水库底泥处理方法。【方法】通过流动度、凝结时间和力学强度等实验,研究水库底泥热活化和化学活化对水库底泥-水泥复合胶凝材料性能的影响。【结果】结果表明,热活化后胶砂试块强度得到提高,但凝结时间大于6.5 h,流动度下降,当热活化温度为700 ℃时,胶砂试块28 d抗折和抗压强度分别为6.71和36.88 MPa,胶砂流动度只有109 mm;热活化-化学活化耦合活化作用下,凝结时间小于6.5 h,流动度上升,当Na2SiO3掺入量为3%时,胶砂流动度提高了13.8%,胶砂试块的28 d 抗折和抗压强度分别为6.98和44.67 MPa。【结论】微观测试结果表明,热活化和化学活化可以促进水库底泥产生更多无定形SiO2参与水化反应,生成更多的水化产物。本研究可以解决水库底泥处理困难的问题,同时为水库底泥的资源化利用提供新思路。

       

      Abstract: Objective The reservoir sediment is large in quantity, and is in fluid and plastic states, and the bearing capacity is poor, and the treatment is difficult, so it is urgent to find the reservoir sediment treatment method. Method The influence of thermal activation and chemical activation of reservoir sediment on the properties of reservoir sediment-cement composite cementitious material was studied by experiments of fluidity, setting time and mechanical strength. Result The results showed that the strength of the mortar specimen was improved after thermal activation, but the setting time was greater than 6.5 h, and the fluidity decreased. When the thermal activation temperature was 700 ℃, the 28 d flexural strength and compressive strength of the mortar specimen were 6.71 and 36.88 MPa, respectively, and the fluidity of the mortar specimen was only 109 mm. At the coupled activation of thermal and chemical activation, the setting time was less than 6.5 h, and the fluidity increased. When the addition of Na2SiO3 was 3%, the fluidity of the mortar increased by 13.8%, and the 28 d flexure and compressive strengths of the mortar specimens were 6.98 and 44.67 MPa, respectively. Conclusion The microcosmic results showed that thermal activation and chemical activation can promote the reservoir sediment to produce more amorphous SiO2 to participate in the hydration reaction and generate more hydration products. This study can solve the difficult problem of reservoir sediment treatment and provide a new idea for the resource utilization of reservoir sediment.

       

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